Work

Bimetallic 2,4-Dichlorophenoxyacetates EU(III) and GD(III): Composition, Structure, and Luminescent Properties

Year: 2025

Type: article

Abstract: The possibility of obtaining different structural types for gadolinium–europium heterometallic complexes by implementing the “structural type memory” effect is described. A series of seven Eu(III)/Gd(III) compounds with 2,4-dichlorophenoxyacetate, having the same composition but belonging to different structural types, was synthesized and structurally characterized. The photoluminescent properties of the obtained compounds were studied. It was shown that compounds crystallizing in the triclinic phase in the P-1 space group exhibit more effective photoluminescence than similar compounds in the monoclinic symmetry with the P21/n space group.

Source: Inorganics

DOI: 10.3390/inorganics13120397

Authors: Oleg Konnik, Alexey Gusev, Elena Braga, Igor Nauhatsky, Maxim Shpak, Natalia Gogoleva, Mikhail Kiskin, Wolfgang Linert

Institutions: V.I. Vernadsky Crimean Federal University, Russian Academy of Sciences, NS Kurnakova Institute of General and Inorganic Chemistry, TU Wien

Language: English

Topic: Lanthanide and Transition Metal Complexes

Subfield: Materials Chemistry

Field: Materials Science

Domain: Physical Sciences

Open Access status: gold

Estimated APC paid: $2,654

OpenAlex ID: W4416948002

FWCI: 0.212

Cites: 39

Cited by: 1

Related to: