Work

Chain-length-dependent reactivity of alkenyl phosphates in ruthenium-catalyzed cross-metathesis

Year: 2025

Type: article

Abstract: Chain length controls fate in Ru-catalyzed cross-metathesis of alkenyl phosphates: vinyl triggers Ru-carbide via proton-coupled phosphate elimination, whereas allyl/butenyl tethers restore productive CM. DFT rationalizes the switch.

Source: Chemical Communications

DOI: 10.1039/d5cc05790f

Authors: Apicha Pontavatchai, Kevin Schwedtmann, Philipp Royla, Kai Schwedtmann, Tossapol Khamnaen, Uwe Schwarzenbolz, Thomas Henle, Ekasith Somsook, Jan J. Weigand

Institutions: Mahidol University, Technische Universität Dresden, SCG Chemicals (Thailand)

Language: English

Topic: Synthetic Organic Chemistry Methods

Subfield: Organic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: hybrid

Funders: Deutsche Forschungsgemeinschaft, SCG Chemicals, Erasmus+

Award: G4792329698

OpenAlex ID: W4416955327

FWCI:

Cites: 22

Cited by:

Related to: