Cobalt Hydroxide‐Organic Frameworks Powering Improved Charge Transfer and Oxygen Evolution Kinetics in Photoelectrochemical Water Splitting
Year: 2025
Type: article
Abstract: Severe charge carrier recombination and sluggish water oxidation kinetics are two critical factors limiting the efficiency of photoanodes for photoelectrochemical (PEC) water splitting. Herein, to address these two issues, a thin layer of cobalt‐based metal hydroxide‐organic framework, namely cobalt hydroxide‐cyanurate framework (Co‐HCF), is successfully grown onto the surface of the promising BiVO 4 photoanode via a simple alcohol‐mediated solvothermal route. When used for PEC water oxidation, the optimized Co‐HCF/BiVO 4 achieved a remarkable photocurrent density of 6.55 mA cm −2 at 1.23 V versus RHE under AM 1.5 G illumination. This performance not only sets a new record for cobalt‐catalyzed undoped BiVO 4 photoanodes, but also surpasses that of all previously reported undoped BiVO 4 photoanodes modified with conventional transition metal (oxy)hydroxides or metal–organic frameworks. Further mechanistic studies reveal that the enhanced PEC water splitting performance arises from the unique microstructure and intriguing physicochemical properties of Co‐HCF, which collectively facilitate interfacial charge transfer and lower the kinetic barrier for water oxidation. This work highlights an effective pathway for the design and fabrication of promising metal hydroxide‐organic frameworks as oxygen evolution cocatalysts for efficient solar energy conversion.
Source: Small
Authors: Baosheng Xie, Xiaozhou Ye, Li Zhang, Liwen Zhang, Jianfeng Ye
Institution: Huazhong Agricultural University
Language: English
Field: Energy
Domain: Physical Sciences
Open Access status: bronze
OpenAlex ID: W4416978863