Year: 2025
Type: article
Abstract: has revealed a previously unreported 1,2-mesityl rearrangement, leading to the formation of α-iridafuran complexes. Comparative analysis with the rhodium analogue as well as different substituents at the propargylic alcohol highlights the unique reactivity of the iridium system, the key role of the mesityl group and the importance of substituent topology.
Source: Dalton Transactions
DOI: 10.1039/d5dt02755a
Authors: Maria Talavera, Antonio Gómez, Nicolás Otero, Ángeles Peña-Gallego, Sandra Bolaño
Institution: Universidade de Vigo
Language: English
Subfield: Organic Chemistry
Field: Chemistry
Domain: Physical Sciences
Open Access status: hybrid
OpenAlex ID: W4416980687