Year: 2025
Type: article
Abstract: -based complex, revealing measurable electric-field effects on the single-ion tensor and setting an upper bound for the SEC influence on magnetic exchange interactions. These findings demonstrate the exceptional sensitivity of EFM-EPR spectroscopy for quantifying SEC and highlight the crucial role of molecular symmetry and ligand environment in enabling electric control of spin states, thus advancing the rational design of molecular systems for quantum technologies.
Source: Chemical Science
DOI: 10.1039/d5sc08012f
Language: English
Field: Materials Science
Domain: Physical Sciences
Open Access status: diamond
Funders: National Science Foundation, U.S. Department of Energy, National High Magnetic Field Laboratory, Dipartimenti di Eccellenza, European Commission, Banca d'Italia, Università degli Studi di Firenze, Ministero dell'Università e della Ricerca, Office of Science, Instituto Nazionale di Fisica Nucleare, Division of Materials Research, Division of Chemistry, Basic Energy Sciences, High Magnetic Field Laboratory, Chinese Academy of Sciences, H2020 European Research Council, State of Florida
Awards: G1019936685, G1868756257, G2120098773, G2792428870, CENTER FOR MOLECULAR MAGNETIC QUANTUM MATERIALS, G3099716454, G3225813136, G3937223104, G5131507077, G5148532935, CENTER FOR MOLECULAR MAGNETIC QUANTUM MATERIALS, G5883309380, MRI: Track 2 Acquisition of Pulsed 9/34 GHz EPR Spectrometer for Quantum Science and Biochemical Research, G6537326076, MRI: Acquisition of a Versatile Magnetic Property Measurement System, National High Magnetic Field Laboratory Renewal 2023-2027, G742574937, G8152425740, G8463808251, G8618556185
OpenAlex ID: W4416986270