Hierarchy of Electrorheological Responses in Aqueous Smectite Clay Dispersions in Relation to DLVO Potential Barriers
Year: 2025
Type: article
Abstract: This study systematically investigated the electrorheological (ER) behavior of four aqueous smectite clay dispersions—fluorinated hectorite (Ht-F), stevensite (Stv), hectorite (Ht), and saponite (Sap)—with emphasis on transparency, rheological responses, and interparticle interactions. Optical observations revealed that the transparency of the aqueous dispersions followed the order Ht-F > Stv > Ht > Sap, which corresponded well to the finer network structures previously observed in Cryo-SEM images. Whereas micrometer-sized poly(methyl methacrylate) (PMMA) dispersions exhibited electrically induced rapid and reversible separation (ERS) due to sedimentation, the nanosized clays, which do not settle, developed ER effects through field-driven flocculation and subsequent network formation. Under low-frequency AC fields, Ht-F showed highly reversible responses similar to Stv, whereas Sap exhibited irreversible stress increases, accompanied by suspected ion release under the field. Dynamic rheological measurements showed that application of electric fields enhanced the loss modulus (G″) more prominently than the storage modulus (G′), clearly indicating a strengthening of viscous behavior. Derjaguin–Landau–Verwey–Overbeek theory (DLVO) potential analysis yielded a barrier-height sequence (Stv < Ht-F < Ht < Sap) that directly paralleled the order of ER responsiveness. These results demonstrate that the ER hierarchy of aqueous smectites can be rationalized by DLVO interactions and provide design guidelines for environmentally compatible ER fluids.
Source: Eng—Advances in Engineering
DOI: 10.3390/eng6120351
Authors: Hiroshi Kimura, Akito Inoue
Institution: Gifu University
Language: English
Subfield: Civil and Structural Engineering
Field: Engineering
Domain: Physical Sciences
Open Access status: gold
Estimated APC paid: $1,448
OpenAlex ID: W4416996365