Year: 2025
Type: article
Abstract: Plasmonic nanohole arrays (NAs) integrating Au and hydrogen-responsive Mg enable dynamic spectral tuning via the Mg → MgH2 transition. Using finite-difference time-domain (FDTD) numerical simulations, we systematically investigate how layer sequence, Au/Mg ratio, total thickness, and stacking number govern extraordinary optical transmission (EOT) resonances. Mg–Au–Mg architectures exhibit the strongest hydrogen response, delivering resonance shifts up to 275 nm and FoM > 1, owing to direct plasmon–hydride coupling at surface Mg layers. Varying the Au/Mg ratio reveals a trade-off: Mg-rich stacks maximize spectral tunability but suffer from broadened, unstable resonances, while Au-rich stacks sustain sharp modes with limited sensitivity; optimal performance arises at intermediate compositions. Thickness dependence shows that ultrathin films (<50 nm) achieve giant shifts (>600 nm) with high contrast, whereas thicker multilayers lose responsiveness. Finally, stacking analysis uncovers an odd–even effect, with Mg-terminated arrays providing larger shifts than Au-terminated ones. These results establish design rules for hydrogen plasmonic sensors, emphasizing resonance engineering through rational layer ordering and composition control.
Source: Technologies
Authors: Jiyu Feng, Yuting Liu, Xinyi Chen, Mingyu Cheng, Bin Ai
Institution: Chongqing University
Language: English
Subfield: Biomedical Engineering
Field: Engineering
Domain: Physical Sciences
Open Access status: gold
Estimated APC paid: $1,930
Award: G3890614147
OpenAlex ID: W4417045487