Work

N-centered, yet persistent: isolation of N 2 O-based radicals through FLP-type stabilization

Year: 2025

Type: article

Abstract: chemical reduction and fully characterized, revealing a highly N-centered nature alongside remarkable persistence at room temperature under an inert atmosphere. A comprehensive investigation of their electronic structure is presented, integrating electron paramagnetic resonance techniques (both continuous-wave and pulsed) with theoretical analysis to provide deeper insight into their properties.

Source: Chemical Science

DOI: 10.1039/d5sc08152a

Authors: Andrea Orellana Ben Amor, Laure Vendier, Vincent César, Vincent Maurel, Julien Panetier, Nicolas Queyriaux

Institutions: Centre National de la Recherche Scientifique, Laboratoire de Chimie de Coordination, Université de Toulouse, Commissariat à l'Énergie Atomique et aux Énergies Alternatives, CEA Grenoble, Institut de Recherche Interdisciplinaire de Grenoble, Université Grenoble Alpes, Binghamton University

Language: English

Topic: Chemical Reactions and Mechanisms

Subfield: Physical and Theoretical Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: diamond

Funders: National Science Foundation, Agence Nationale de la Recherche, Université de Toulouse, Centre National de la Recherche Scientifique, Division of Chemistry

Awards: Nitrous Oxide (N2O) : electro-assisted catalytic deoxygenation and beyond, G2870243475, G4180087395, CAS: Computational Modeling of Carbon Monoxide Dehydrogenase Model Systems for Carbon Dioxide Fixation

OpenAlex ID: W4417152871

FWCI: 2.183

Cites: 61

Cited by: 5

Related to: