Optical control of a metastable phase in the charge density wave Mott insulator 1 T − TaS 2 investigated using time- and angle-resolved photoemission spectroscopy
Year: 2025
Type: article
Abstract: Light-induced metastable phases are exotic, long-lived out-of-equilibrium states of matter. Optical control offers a powerful approach to engineering these phases, enabling dynamic tuning of their electronic and structural properties. Using time- and angle-resolved photoemission spectroscopy, we investigate the emergence of a metastable phase induced by a strong infrared pump in the charge-density-wave (CDW)-Mott insulator 1 T − TaS 2 . Furthermore, we demonstrate how its properties can be optically manipulated by varying the photoexcitation strength. A long-lived stabilization of the renormalized electronic band structure serves as a signature of the metastable phase. It displays a relaxed periodic lattice distortion (PLD) and primarily lattice-driven dynamics. The emergence of a new dispersive band in the vicinity of the Hubbard bands reveals the formation of a novel band structure unique to the metastable phase. Our pump-fluence-dependent studies reveal a threshold (incident) fluence F C ∼ 1.3 mJ / cm 2 for inducing the metastable phase, above which the band renormalization continuously evolves with increasing fluence. For F ⩽ 3.4 mJ / cm 2 , stronger photoexcitation progressively drives the phase to higher energies, accompanied by a more relaxed PLD and reduced CDW amplitude. The properties of the metastable phase are strongly influenced by the transient dynamics at each fluence, and the associated fast timescales suggest that the intrinsic CDW amplitude mode remains unaffected by optical manipulation. These findings highlight the potential of optical control in tuning the properties of metastable phases in quantum materials, offering new insights into the manipulation of CDW systems and paving the way for future investigations in nonequilibrium phase engineering.
DOI: 10.1103/gz2s-685y
Authors: Tanusree Saha, Arindam Pramanik, Rokaya Osama, Fabio Frassetto, Damjan Krizmancic, Luca Poletto, Arun Ravindran, Barbara Ressel, Primož Rebernik Ribič, Giovanni De Ninno
Language: English
Subfield: Atomic and Molecular Physics, and Optics
Field: Physics and Astronomy
Domain: Physical Sciences
Open Access status: hybrid
OpenAlex ID: W4417267992