Development and Characterization of LDPE/Vermiculite Composites: Effects on Mechanical, Thermal, and Morphological Properties
Year: 2025
Type: article
Abstract: ABSTRACT In this study, vermiculite (VMT), a naturally occurring layered silicate, was incorporated into a low‐density polyethylene (LDPE) matrix at loading levels of 5 wt%, 7.5 wt%, 10 wt%, and 15 wt%. The composites were prepared by melt blending using a twin‐screw extruder followed by injection molding. Thermal, mechanical, morphological and structural characterizations were conducted through thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), tensile and flexural tests, Izod notched impact testing, scanning electron microscopy (SEM), and Fourier transform infrared spectroscopy (FTIR). TGA results indicated an increase in thermal degradation onset temperature from 357 °C (neat LDPE) to 389 °C (15 wt% VMT), confirming enhanced thermal stability. DSC analysis showed a slight reduction in crystallinity with increasing VMT content. The tensile and flexural moduli were improved proportionally with VMT loading, suggesting a stiffening effect, while elongation at break and impact resistance decreased, implying reduced ductility. SEM observations revealed good filler dispersion at low concentrations, but particle agglomeration and interfacial voids became evident at higher loadings. FTIR spectra confirmed the presence of VMT without any significant chemical interaction with the LDPE backbone. Overall, the incorporation of VMT enhances the rigidity and thermal resistance of LDPE composites, making them promising candidates for structural applications where dimensional stability and thermal performance are critical.
Source: ChemistrySelect
Author: Ayşenur Yeşilyurt
Institution: Bursa Technical University
Language: English
Subfield: Polymers and Plastics
Field: Materials Science
Domain: Physical Sciences
Open Access status: green
OpenAlex ID: W4417285987