Structure–optical–dielectric correlations in ordered double perovskites Sr2(Co Zn )TeO6 (0 ≤ x ≤ 1)
Year: 2025
Type: article
Abstract: The double perovskite series Sr 2 (Co 1-x Zn x )TeO 6 ( x = 0, 0.25, 0.50, 0.75, 1 ) has been synthesized and systematically investigated to establish the correlations between structure, optical response, and dielectric behavior. Powder X-ray diffraction and Rietveld refinement confirm that Sr 2 CoTeO 6 crystallizes in the monoclinic P 2 1 / n structure, Sr 2 ZnTeO 6 in I2/m, and the intermediate compositions in I 2/ m as well. Structural refinements reveal opposite compositional trends in Co/Zn–O and Te–O bond lengths, directly influencing the vibrational dynamics: Raman spectra display progressive blue-shifts of Te–O stretching modes, particularly near 750 cm −1 . Optical diffuse reflectance measurements, analyzed via Tauc and derivative absorption spectroscopy fitting, show a systematic widening of the band gap from 3.21 eV ( x = 0 ) to 4.13 eV ( x = 1 ), consistent with the reduction of Co 2+ contributions near the band edge. Dielectric spectroscopy further highlights a strong dependence on composition. While Zn-rich members exhibit insulating behavior with stable permittivity and low loss over 100 Hz–1 MHz, the Co-rich end member Sr 2 CoTeO 6 displays an anomalous dispersion with a crossover from Maxwell–Wagner interfacial polarization to dipolar polarization at ∼300 kHz, as confirmed by Cole–Cole analysis (ε s ≈ 320, τ ≈ 3.3 μs). This unusually high transition frequency stabilizes the dielectric response over a broad frequency window. Taken together, these results demonstrate clear structure–optical–dielectric correlations across the Sr 2 (Co 1-x Zn x )TeO 6 series. The Co-rich composition combines a high permittivity and frequency stability, underscoring its potential for dielectric capacitor applications, while Zn substitution tunes the material toward wider band gaps and enhanced optical insulation.
Source: Journal of Solid State Chemistry
Institutions: University of Bremen, University of Glasgow
Language: English
Subfield: Materials Chemistry
Field: Materials Science
Domain: Physical Sciences
Open Access status: hybrid
Estimated APC paid: $3,540
Award: G1298884883
OpenAlex ID: W4417289999