Work

Synthesis and Investigation of Bonding Scenario in a Bis(silaselenone)

Year: 2025

Type: article

Abstract: The compounds containing SiSe bond, are rarely reported in the literature. Silaselenones are the class of compounds that possess SiSe bond. Herein, we report a bis(silaselenone) ( 3 ) that contains two SiSe bonds. The compound 3 was characterized by single‐crystal X‐ray diffraction, mass spectrometry, and NMR spectroscopy. The nature of bonding in compound 3 has been studied by employing natural bond orbital analysis and energy decomposition analysis‐natural orbital for chemical valence (EDA‐NOCV). The bonding analysis by employing EDA‐NOCV method showed that compound 3 possesses two electron sharing covalent sigma bonds between the silicon atoms of silylene and SiPh 2 group.

Source: European Journal of Inorganic Chemistry

DOI: 10.1002/ejic.202500596

Authors: Saroj Kumar Kushvaha, Harsha S. Karnamkkott, Paula A. M. Stark, Sai Manoj N. V. T. Gorantla, Regine Herbst‐Irmer, Kartik Chandra Mondal, Dietmar Stalke, Herbert W. Roesky

Institutions: University of Göttingen, Indian Institute of Technology Madras, UiT The Arctic University of Norway

Language: English

Topic: Synthesis and characterization of novel inorganic/organometallic compounds

Subfield: Inorganic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: hybrid

Estimated APC paid: $4,050

OpenAlex ID: W4417306701

FWCI:

Cites: 33

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