Work

Reductive deoxygenation of tertiary alcohols: a cobalt-catalyzed hydrosilylation approach

Year: 2025

Type: article

Abstract: catalyzed hydrosilylation protocol for the reductive deoxygenation of tertiary alcohols involving a radical mechanism. Successful deoxygenation of various tertiary, secondary and primary alcohols demonstrated the broad applicability, including syntheses of fine chemicals. A plausible mechanistic path was proposed based on several control experiments.

Source: Organic & Biomolecular Chemistry

DOI: 10.1039/d5ob01788b

Authors: Swetarani Meher, Ratiraman Swain, Braja Kishore Marndi, Bidraha Bagh

Institutions: National Institute of Science Education and Research, Homi Bhabha National Institute

Language: English

Topic: Asymmetric Hydrogenation and Catalysis

Subfield: Inorganic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: hybrid

Funders: Department of Atomic Energy, Government of India, National Institute of Science Education and Research, Science and Engineering Research Board

Awards: G153121861, G7054756565