Work

An Ecofriendly Approach to Obtain Biodegradable Hydrogels by Reactive Extrusion

Year: 2025
Type: article
Abstract: Climate change and the impacts related to nonbiodegradable synthetic materials highlight the need for sustainable alternatives. Biopolymers from renewable sources show great potential for producing hydrogels, which are three-dimensionally crosslinked materials with high water absorption. In this work, super-absorbent biodegradable hydrogels were produced via single-step reactive extrusion using mixtures of starch, gelatin, cellulose, and xanthan gum, with glycerol as a plasticizer, and citric acid as a crosslinking agent. Pelleted hydrogels were obtained with water absorption between 290% and 363%. Reactive extrusion promoted the formation of new ester and amide bonds, confirmed by FT-IR. Citric acid was effective as a crosslinker, and higher citric acid content (3%) produced samples with greater swelling, supported by the porous internal structure observed. Preliminary agricultural tests showed that the formulation with the highest citric acid content, when added to soil at 5%, significantly increased water-holding capacity and resulted in the highest germination rate of maize seeds. Overall, the extrusion process proved efficient, scalable, and environmentally friendly for producing biodegradable hydrogels for agricultural applications.
Source: Biomass
Language: English
Open Access status: gold
Estimated APC paid: $1,207
OpenAlex ID: W4417457170
FWCI:
Cites: 71
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