Interplay of Cationic Site Occupancy in Mn-Co Spinel Oxides: Correlating Structural, Vibrational, Morphological, and Electrochemical Properties
Year: 2025
Type: article
Abstract: MnCo2O4 and CoMn2O4 were successfully synthesized on a stainless-steel substrate using the hydrothermal method. The structural and morphological characteristics of the spinel samples were investigated using X-ray diffraction (XRD) and scanning electron microscopy (SEM). The electronic and vibrational properties were studied through X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared spectroscopy (FTIR). Electrochemical properties were also evaluated using a three-electrode system associated with an electrochemical workstation. The studies revealed that the inversion of Mn and Co cation distribution between the spinel structure sites not only modifies the crystal structure and morphology but also alters specific functional properties. MnCo2O4 crystallized in a cubic spinel phase, exhibiting spherical particles, pronounced microstrain, and stronger metal–oxygen bonding. In contrast, CoMn2O4 adopted a tetragonal spinel structure with rod-like crystallites, lower microstrain, and more flexible bonding environments. Electrochemical impedance spectroscopy further revealed distinct charge-transfer dynamics, indicating differences in surface redox activity. This comparative analysis elucidates how cation site occupancy governs the performance of the synthesized spinel oxides and underscores their potential as efficient catalysts or catalyst supports for redox and energy-related applications.
Source: Applied Sciences
DOI: 10.3390/app152413267
Language: English
Subfield: Electrical and Electronic Engineering
Field: Engineering
Domain: Physical Sciences
Open Access status: gold
Estimated APC paid: $2,896
OpenAlex ID: W4417461845