Year: 2025
Type: article
Abstract: We report a highly diastereoselective hydrosulfenation of cyclopropenes to synthesize cyclopropyl sulfoxides. Mechanistic studies reveal that exo / endo , facial and side selectivities collectively governed stereocontrol over up to 8 diastereomers.
Source: Chemical Science
DOI: 10.1039/d5sc08731g
Authors: Liyan Yuwen, Jiazhong Tang, Yayu Qi, Tianyi Zou, Shaotong Zhang, Ya-Qian Zhang, Qing-Wei Zhang
Institution: University of Science and Technology of China
Language: English
Subfield: Organic Chemistry
Field: Chemistry
Domain: Physical Sciences
Open Access status: diamond
Awards: G3435604224, G6922333407
OpenAlex ID: W4417498663