Reconstruction of the Passive Layer of AISI 304 and 316 Steel After Scratching
Year: 2024
Type: article
Abstract: Austenitic stainless steels are used widely in many fields due to their good mechanical properties and high resistance to corrosion. This work focuses on the reconstruction of the passive film after scratching. The purpose of the study was to compare changes in the rate of passive layer reconstruction and to discuss the effect of both the type of material and its electrochemical treatment on the reconstruction of the passive layer for two types of stainless steel: 304 and 316. The XPS tests performed indicate a significantly higher Cr/Fe ratio for the samples after the electropolishing process of 1.41–1.88 compared to the as-received samples of 0.82–0.86. After 2–3 min of sputtering the surface with Ar+ ions, a decrease in chromium content can be observed, with a simultaneous increase in nickel content, visible especially for the electropolished samples. A new approach in the conducted research was to scratch the test samples under controlled conditions, then evaluate the dynamics of the passive layer reconstruction using the AFM method, and then confront the obtained results with XPS measurements for the corresponding samples. For the as-received samples (2B finish) and those after surface treatment, regardless of the level of contamination of the electropolishing process bath, the reconstruction time was similar, which was approximately 2 h, although certain differences in the process dynamics were noticeable.
Language: English
Subfield: Metals and Alloys
Field: Materials Science
Domain: Physical Sciences
Open Access status: green
Funder: European Commission
Award: G3287971284
OpenAlex ID: W6912099198
FWCI:
Cites:
Cited by:
Related to: