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π‐Lewis Base Activation of Carbonyls and Hexafluorobenzene

Year: 2025

Type: article

Abstract: We report hitherto elusive side‐on η2‐bonded palladium(0) carbonyl (anthraquinone, benzaldehyde) and arene (benzene, hexafluorobenzene) palladium(0) complexes and present the catalytic hydrodefluorination of hexafluorobenzene by cyclohexene. The comparison with respective cyclohexene, pyridine and tetrahydrofuran complexes reveals that the experimental ligand binding strengths follow the order THF

Source: Refubium (Universitätsbibliothek der Freien Universität Berlin)

DOI: 10.17169/refubium-47292

Authors: Mondal, Aditesh, Breitwieser, Kevin, Danés, Sergi, Grünwald, Annette, Heinemann, Frank W., Morgenstern, Bernd, Müller, Frank, Haumann, Michael, Schütze, Maximilian, Kass, Dustin, Ray, Kallol, Munz, Dominik

Language: English

Topic: Organometallic Complex Synthesis and Catalysis

Subfield: Organic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: green

Funders: European Commission, Friedrich-Alexander-Universität Erlangen-Nürnberg, Deutsche Forschungsgemeinschaft, Universität des Saarlandes

Awards: EXC 2008: Unifying Systems in Catalysis "UniSysCat", G159631992, G1875865334, G2357260730, HochleistungscomputeCluster, G434337789, G4966056885, G6690480278, G8018889347, G8136362559

OpenAlex ID: W6962253133

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