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π‐Lewis Base Activation of Carbonyls and Hexafluorobenzene

Year: 2024

Type: article

Abstract: We report hitherto elusive side‐on η2‐bonded palladium(0) carbonyl (anthraquinone, benzaldehyde) and arene (benzene, hexafluorobenzene) palladium(0) complexes and present the catalytic hydrodefluorination of hexafluorobenzene by cyclohexene. The comparison with respective cyclohexene, pyridine and tetrahydrofuran complexes reveals that the experimental ligand binding strengths follow the order THF

Source: edoc Publication server (Humboldt University of Berlin)

DOI: 10.18452/33297

Authors: Mondal, Aditesh, Breitwieser, Kevin, Danés, Sergi, Grünwald, Annette, Heinemann, Frank W., Morgenstern, Bernd, Müller, Frank, Haumann, Michael, Schütze, Maximilian, Kass, Dustin, Ray, Kallol, Munz, Dominik

Language: English

Topic: Organometallic Complex Synthesis and Catalysis

Subfield: Organic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: green

OpenAlex ID: W6963491095

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