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High molecular weight PE elastomers through 4,4-difluorobenzhydryl substitution in symmetrical α-diimino-nickel ethylene polymerization catalysts

Year: 2022

Type: article

Abstract: N , N -Diaryl-2,3-dimethyl-1,4-diazabutadiene-nickel complexes appended with 4,4-difluorobenzhydryl groups can efficiently mediate the formation of polyethylene elastomers with molecular weights approaching one million g mol −1 .

Source: RSC Advances

DOI: 10.1039/d2ra04321a

Authors: Yuting Zheng, Shu Jiang, Ming Liu, Zhixin Yu, Yanping Ma, Gregory A. Solan, Wenjuan Zhang, Tongling Liang, Wen-Hua Sun

Institutions: Chinese Academy of Sciences, Beijing National Laboratory for Molecular Sciences, Changchun University of Chinese Medicine, Institute of Chemistry, University of Leicester, Beijing Institute of Fashion Technology

Language: English

Topic: Organometallic Complex Synthesis and Catalysis

Subfield: Organic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: gold

Estimated APC paid: $1,042

Funders: National Natural Science Foundation of China, Chinese Academy of Sciences

Award: 精密调控铁（钴）配合物催化乙烯聚合制备高度线性和窄分布聚乙烯

OpenAlex ID: W4294010011

FWCI: 0.924

Cites: 86

Cited by: 12

Related to: 9