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Reversible CO₂ insertion into the silicon–nitrogen σ-bond of an N-heterocyclic iminosilane

Year: 2024

Type: article

Abstract: The reversible insertion of carbon dioxide into the silicon–nitrogen bond of an N-heterocyclic iminosilane is reported. Solution-phase thermodynamic investigations indicate that this process is thermoneutral and reversible, whereas in the solid-phase CO₂ can be stored for extended periods and is only released upon heating to 133 °C.

Source: UCL Discovery (University College London)

Authors: Wang, Jingyan, Hwang, Gi Byoung, Knapp, Caroline E, Wilson, Daniel WN

Language: English

Topic: Carbon dioxide utilization in catalysis

Subfield: Process Chemistry and Technology

Field: Chemical Engineering

Domain: Physical Sciences

SDG: Climate action

Open Access status: green

OpenAlex ID: W7061830464

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