Work

Measurements of thermodynamic properties and activity coefficients at infinite dilution of selected organic solutes and water in a deep eutectic solvent (choline chloride +1,3 propanediol)

Year: 2025

Type: article

Abstract: In this study, a deep eutectic solvent (DES) consisting of choline chloride (ChCl) and 1,3 propanediol (Pdiol) at a 1:2 M ratio was evaluated experimentally for its extractive efficiency. The important DES's physicochemical properties: density, viscosity, and refractive index, were measured at T = (293.15–353.15) K and 101.3 kPa. Solvent intermolecular interaction strengths against 32 selected organic solutes were assessed using experimental infinite dilution activity coefficients (IDAC) measured at T = (313.15 to 343.15) K and 101.3 kPa. The interactions between the solute and solvent molecules were further characterised by partial molar excess properties ( Δ H i E , ∞ , Δ G i E , ∞ and T ref Δ S i E , ∞ ). The separation ability of the solvent was assessed using selectivity ( S ij ∞ ) and capacity ( k j ∞ ) as thermodynamic separation parameters. DES indicated stronger interactions with more polar molecules. The findings indicate that DES is suitable for separating the alkanes from alcohols, acetonitrile or thiophene mixtures. This work adds to the DES database and offers a theoretical framework for industrial separation problems. • Infinite dilution activity coefficients data were determined using the GLC method. • The structure and polarity of a solute strongly influence its strength of interaction. • Investigated DES exceeds prior diol-based DES for selected industrial separations. • The studied DES exhibits high separation efficiency and green extractant potential.

Source: Journal of Molecular Liquids

DOI: 10.1016/j.molliq.2025.128320

Authors: Banzi P. Mbatha, Peterson T. Ngema, Suresh Ramsuroop, Kaniki Tumba, Lindokuhle Manyoni, Nkululeko Nkosi

Institutions: Durban University of Technology, Cape Peninsula University of Technology, North-West University, Mangosuthu University of Technology

Language: English

Topic: Ionic liquids properties and applications

Subfield: Catalysis

Field: Chemical Engineering

Domain: Physical Sciences

Open Access status: hybrid

Estimated APC paid: $3,480

Funders: Durban University of Technology, National Research Foundation, Mangosuthu University of Technology