Work

Low-cost transition metals (Fe, Ni, Co) on carbon aerogel for water electrolysis and supercapacitor applications

Year: 2025

Type: article

Abstract: • Transition metal (Fe, Ni, Co) nanoparticles are grafted on carbon aerogel by microwave irradiation. • Further N 2 -doping led to TM NPs size increase and conversion to amorphous carbon structure. • Co/CA demonstrates the best performance for OER with a low η 10 of 276 mV and high stability. • Fe/CA delivers high specific capacitance of 320 Fg -1 at 10 mV s -1 with high cycling stability. Cost-effective transition metals (TM = Fe, Ni, Co) were immobilized on carbon aerogel (CA) using microwave irradiation, followed by nitrogen doping into one catalyst series through heat treatment. The physical characterization of the synthesized catalysts included N 2 sorption, inductively coupled plasma-mass spectrometry, X-ray diffraction analysis, transmission electron microscopy, Raman spectroscopy, FTIR spectroscopy, and X-ray photoelectron spectroscopy. Co/CA displayed the best performance for oxygen evolution reaction (OER) electrocatalysis in alkaline water electrolysis, followed by Ni/CA. Co/CA exhibited a small Tafel slope of 110 mV dec −1 and required an overpotential of just 276 mV to reach 10 mA cm −2 , lower than that of the commercial IrO 2 electrocatalyst. Additionally, Co/CA and Ni/CA demonstrated excellent long-term stability during OER, with activity increasing over time. Capacitance measurements also showed the potential of TM/CA materials as supercapacitor electrodes. Fe/CA achieved the highest performance, with a specific capacitance of 322 F g -1 at a moderate current of 1 A g -1 . It retained up to 96 % of its capacitance over 1000 cycles, indicating excellent stability.

Source: Electrochimica Acta

DOI: 10.1016/j.electacta.2025.147226