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Cover Feature: Single‐Atom Based Metal‐Organic Frameworks for Efficient C−S Cross‐Coupling (Chem. Asian J. 7/2025)

Year: 2025

Type: article

Abstract: Jayaramulu Kolleboyina and co-workers engineered a nickel single-atom catalyst (UiO-66/Ni) with Ni atoms covalently anchored to defect-engineered Zr-oxide clusters in the UiO-66 framework, synthesized via a simple solution impregnation method. This catalyst shows uniform Ni atom distribution, exceptional stability, and high catalytic performance in C–S coupling reactions of aryl thiols and aryl halides, achieving high activity and selectivity across various substituents at room temperature, maintaining stability. More details can be found in article number e202401578.

Source: Chemistry - An Asian Journal

DOI: 10.1002/asia.202580702

Authors: Gobbilla Sai Kumar, Deepak Kumar, Aditya Thakur, Mukul Gupta, Praveen Kumar Velpula, Rabindranath Lo, Kolleboyina Jayaramulu

Institutions: Indian Institute of Technology Jammu, UGC DAE Consortium for Scientific Research, Czech Academy of Sciences, Czech Academy of Sciences, Institute of Organic Chemistry and Biochemistry

Language: English

Topic: Metal-Organic Frameworks: Synthesis and Applications

Subfield: Inorganic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: bronze

OpenAlex ID: W7085831567

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