Work

Bis-guanidinate magnesium amide-catalyzed hydroboration of nitriles and isocyanides via a substrate-assisted pathway

Year: 2025

Type: article

Abstract: Magnesium catalysis : A bis-guanidinate magnesium amido complex enables the first example of a substrate-assisted catalytic dihydroboration of nitriles and isocyanides, with the isolation of key intermediates and elucidation of catalytic cycles.

Source: Organic Chemistry Frontiers

DOI: 10.1039/d5qo01184a

Authors: Sayantan Mukhopadhyay, Smrutirani Padhan, Anubhab Das, Sharanappa Nembenna

Institution: National Institute of Science Education and Research

Language: English

Topic: Organoboron and organosilicon chemistry

Subfield: Organic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: hybrid

Funders: National Institute of Science Education and Research, Homi Bhabha National Institute, Science and Engineering Research Board

Award: G6275826580