Reconstruction of the benzene absorption band at 14.8 μm in amplitude modulation exploiting a quartz tuning fork as optical detector
Year: 2025
Type: article
Abstract: This work presents a single-pass optical sensor designed for the detection of a broadband absorption feature of benzene. It is based on light-induced thermoelastic absorption spectroscopy (LITES) employing a novel InAs/AlSb-based quantum cascade laser source emitting at 14.85 μm as light source, and a custom-designed quartz tuning fork (QTF) as infrared photodetector. The sensor system was operated in both amplitude (AM) and wavelength modulation (WM) mode to characterize the absorption band parameters and assess the sensor ultimate detection limit. The limitations of WM and double-frequency detection (2f-WM) approach for broadband absorption features are thoroughly analyzed and discussed. An absorption cross-section of (1.1 ± 0.1) · 10 cm 2 was measured in AM mode with a minimum detection limit of 1.6 part-per-million, while a minimum detection limit of 0.6 part-per-million was achieved using the 2f-WM mode, at 0.1 s of integration time, employing a 12 cm long single-pass cell.
Source: Sensors and Actuators A Physical
Authors: Andrea Zifarelli, Lavinia Anna Mongelli, Kumar Kinjalk, Alexei Baranov, Pietro Patimisco, Qijie Wang, Vincenzo Spagnolo, Angelo Sampaolo
Institutions: University of Bari Aldo Moro, Polytechnic University of Bari, Centre National de la Recherche Scientifique, Université de Montpellier, Institut d'Électronique et des Systèmes, Laboratoire d'Analyse et d'Architecture des Systèmes, Université de Toulouse, Nanyang Technological University, Centre for Disruptive Photonic Technologies
Language: English
Subfield: Spectroscopy
Field: Chemistry
Domain: Physical Sciences
Open Access status: hybrid
Estimated APC paid: $3,750
Awards: G5076356484, G6352741880
OpenAlex ID: W7104009738
