Work

Development of a multi-zone adiabatic reactor optimization framework for oxidative coupling of methane

Year: 2025

Type: article

Abstract: Managing heat is a major challenge for oxidative coupling of methane (OCM) because of its high exothermicity. While recent innovations have mainly focused on reactor design, most studies assume isothermal operation, which is often impractical for scale-up. Adiabatic operation better reflects industrial conditions but remains underexplored. Additionally, little attention has been given to distributing O 2 along the reactor or using interstage cooling to smooth temperature variations inside the OCM reactor and improve performance. In this work, we address those gaps by optimizing a multi-zone reactor design with distribution feeding of O 2 . Using Simulated Annealing, we model up to 30 reactor zones, each treated as a fixed-bed, one-dimensional and pseudo-homogeneous system. Our results show that distributing oxygen across multiple zones with interstage cooling increases the C 2 yield by almost 8 times, from 5.7% in a single zone to 46.5 % across 30 zones, achieving smoother temperature profiles without changing the catalyst.

Source: Chemical Engineering Science

DOI: 10.1016/j.ces.2025.123040

Authors: Murtaza Ali Khan, Mamoun Al-Rawashdeh, Patrick Linke

Institutions: Texas A&M University at Qatar, Texas A&M University, Hamad bin Khalifa University

Language: English

Topic: Catalysis and Oxidation Reactions

Subfield: Catalysis

Field: Chemical Engineering

Domain: Physical Sciences

SDG: Affordable and clean energy

Open Access status: hybrid

Estimated APC paid: $4,050