Work

Electronic structure origins of radical character in triangular fused acenes: sextet stabilization vs. antiaromaticity release

Year: 2025

Type: article

Abstract: Triangular acenes display size-dependent radical character arising from the interplay between Clar's sextet stabilization and the release of cyclobutadiene antiaromaticity.

Source: Organic Chemistry Frontiers

DOI: 10.1039/d5qo01343g

Authors: José Aarón Rodríguez-Jiménez, Jan Patrick Calupitan, David Casanova

Institutions: University of the Basque Country, Donostia International Physics Center, Centre National de la Recherche Scientifique, Sorbonne Université, Material Physics Center, Institut Parisien de Chimie Moléculaire, Ikerbasque

Language: English

Topic: Synthesis and Properties of Aromatic Compounds

Subfield: Organic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: hybrid

Funders: Ministerio de Ciencia, Innovación y Universidades, Ikerbasque, Basque Foundation for Science, Sorbonne Université, Agencia Estatal de Investigación, H2020 Marie Skłodowska-Curie Actions

Awards: G103507813, G1072458704, G1105844351, G1175115578, G1270065135, G2262748287, G300979063, G3480869486, G3834952833, G425668148, G491712853, G5080475149, G5209569390, G5529682524, G6316114756, G7084143925, G7805626310, G7863371703, G8497050386

OpenAlex ID: W7106815837

FWCI:

Cites: 63

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