A proposed route to metastable room-temperature superconductivity in Li₂MgB₂H₁₈
Year: 2025
Type: article
Abstract: The realization of room-temperature superconductivity at ambient pressure remains the ultimate goal of condensed matter physics. While high-pressure superhydrides (e.g., 𝐿𝑎𝐻10) have achieved high critical temperatures (Tc), they lose stability upon decompression. Here, I predict a novel ternary clathrate structure, 𝐿𝑖2 𝑀𝑔 𝐵2𝐻18, designed to maintain high-Tc superconductivity at 0GPa via a "kinetic locking" mechanism. First-principles calculations reveal that a rigid Boron-Magnesium host lattice can chemically confine dense hydrogen clusters, mimicking the effects of external pressure. I estimate a Tc of ~298 K driven by strong electron-phonon coupling (𝜆≈2.6). Furthermore, I propose a cryogenic decompression protocol ("Cryo-Lock") to synthesize and stabilize this metastable phase for ambient-pressure operation
Author: Travaglini, Giustino
Language: English
Subfield: Geophysics
Field: Earth and Planetary Sciences
Domain: Physical Sciences
Open Access status: green
OpenAlex ID: W7108209092
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