Work

Synthesis, crystal structure and Hirshfeld surface of bis(acetato-κ 2 O , O ′)(2-benzyl-1 H -benzimidazole-κ N 3 )copper(II)

Year: 2025

Type: article

Abstract: The title copper(II) complex, [Cu(C 2 H 3 O 2 ) 2 (C 14 H 12 N 2 ) 2 ], was synthesized and structurally characterized. It crystallizes in the monoclinic space group P2 1 /n with one molecule per asymmetric unit. The Cu 2+ ion exhibits a distorted octahedral (4 + 2) coordination geometry. The crystal packing is consolidated by N—H...O hydrogen bonds and C—H...π interactions. Hirshfeld surface analysis indicates that H...H, H...C/C...H and O...H/H...O contacts are the major contributors to the crystal packing.

Source: Acta Crystallographica Section E Crystallographic Communications

DOI: 10.1107/s2056989025010813

Authors: Gulnoza Boboyeva, Gulbeka Mamatova, Sardor Murodov, Komila Ganiyeva, Kambarali Turgunov, Bakhodir Tashkhodjaev, Shakhlo Daminova

Institutions: Tashkent State Medical University, National University of Uzbekistan, D. Mendeleyev University of Chemical Technology of Russia, Academy of Sciences Republic of Uzbekistan, Yunusov Institute of the Chemistry of Plant Substances

Language: English

Topic: Crystal structures of chemical compounds

Subfield: Inorganic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: gold

Estimated APC paid: $500

Funder: Academy of Sciences Republic of Uzbekistan