When halogen bonding isn't enough: solvation behavior in ionic cocrystals of benzyltrimethylammonium halides and 1,4-diiodotetrafluorobenzene
Year: 2025
Type: article
Abstract: Crystallization of 1,4-diiodo-tetrafluorobenzene with trimethylbenzyl ammonium halides (NMe 3 BzX, X = Cl, Br, I) shows anion and solvent dependence: NMe 3 BzI favors solvated 1 : 1 cocrystals, while NMe 3 BzBr and NMe 3 BzCl favor unsolvated 1 : 1 networks.
Source: CrystEngComm
DOI: 10.1039/d5ce00832h
Authors: Andrew J. Peloquin, Lahiruni Pelendage, Srikar Alapati, Timothy W. Hanks, Colin D. McMillen, William T. Pennington
Institutions: Clemson University, Furman University
Language: English
Subfield: Physical and Theoretical Chemistry
Field: Chemistry
Domain: Physical Sciences
Open Access status: hybrid
OpenAlex ID: W7109960434