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Ovrednotenje cementnih kompozitov z recikliranim agregatom, onesnaženim s težkimi kovinami - v smeri trajnostne uporabe

Year: 2025
Type: article
Abstract: The use of recycled aggregate provides clear environmental advantages but may in-troduce chemical interactions that influence cement hydration, particularly when the material originates from mining by-products containing heavy metals. This study ex-amines cementitious composites containing different volume fractions of recycled ag-gregate derived from Pb–Zn mine tailings and identifies the mechanisms responsible for the observed early-age hydration delay. The recycled aggregate was characterized using XRD, hydration was monitored through ultrasonic pulse velocity (UPV) and temperature evolution, mechanical performance was assessed at 1, 3, and 7 days, and phase evolution was interpreted using SEM-EDS and thermodynamic equilibrium modeling (GEMS/Cemdata18). The results show that heavy-metal-bearing phases (Zn-, Pb-, and Fe-sulfides/sulfates) promote the formation of metastable metal–silicate complexes, temporarily lowering the oxidation potential and d elaying setting by up to 28 h in mixtures containing 100% recycled aggregate. Early-age strength was substantially reduced
Authors: Turk, Tilen, Štukovnik, Petra, Marinšek, Marjan, Bokan-Bosiljkov, Violeta
Language: English
Open Access status: green
OpenAlex ID: W7115219986
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