Work

Design of boron-decorated bimetallic iron complexes related to the active site of [FeFe]-hydrogenases and reactivity with hydride donors

Year: 2025

Type: article

Abstract: The reaction of HB(C 6 F 5 ) 2 with 1,2-dithiolene diiron complexes affords the first examples incorporating Lewis acidic borane moieties, allowing their reactivity toward hydride donors to be explored.

Source: Dalton Transactions

DOI: 10.1039/d5dt02885j

Authors: Ines Bennour, Victor Monnot, Philippe Schollhammer, Lucile Chatelain

Institutions: Centre National de la Recherche Scientifique, Université de Bretagne Occidentale, Laboratoire Chimie Electrochimie Moléculaires et Chimie Analytique

Language: English

Topic: Metalloenzymes and iron-sulfur proteins

Subfield: Renewable Energy, Sustainability and the Environment

Field: Energy

Domain: Physical Sciences

Open Access status: green

Funders: Agence Nationale de la Recherche, Région Bretagne

Award: Tandem reactivity of a redox-active Frustrated Lewis Pair for H2 oxidation on [FeFe]-platform

OpenAlex ID: W7116775767

FWCI: 0.139

Cites: 77

Cited by: 1

Related to: