Year: 2025
Type: article
Abstract: Understanding ferroelectric phase stability in hafnium-based oxides is crucial for high-quality thin-film fabrication and device applications. Multiple strategies stabilize the phase, with evidence highlighting extra holes’ key role. However, research on extra holes’ impact on ferroelectric phase stabilization remains inadequate. This study combines first-principles calculations with experimental data, identifying a critical extra-hole concentration threshold (0.3 h/f.u.) for HfO 2 ferroelectric phase stabilization. We designed two coordinated experiments to verify the extra-hole threshold in HfO 2 . Using SrRuO 3 (SRO) as the bottom electrode, we studied three HfO 2 systems (Sm, Eu, and La doped). All systems showed optimal ferroelectric performance at 7.5% doping. Our results also showed that HfO 2 films on Sm-doped (La 0.67 Sr 0.33 MnO 3 ) LSMO (5.5% doping) achieve optimal polarization, comparable to SRO (7.5%). These mutually corroborative experimental and theoretical results indicate that the extra-hole threshold optimizes HfO 2 ferroelectric thin film growth and facilitates its electronic device applications.
Source: Communications Physics
Language: English
Subfield: Electrical and Electronic Engineering
Field: Engineering
Domain: Physical Sciences
Open Access status: gold
Estimated APC paid: $3,990
Award: G2309645728
OpenAlex ID: W7117130814