Work

The crystal structure of potassium 1-(2,2″,4,4″,6,6″-hexamethyl-[1,1′:3′,1″-terphenyl]-2′-yl)-2,2-diisopropyldiphosphane-1-carbodithioate n -hexane solvate, C 124 H 156 K 4 P 8 S 8 , 2(C 6 H 14 )

Year: 2025

Type: article

Abstract: C 136 H 184 K 4 P 8 S 8 , triclinic, P 1 ̅ $̅{1}$ (no. 2), a = 12.4391(7) Å, b = 17.2716(9) Å, c = 17.9250(9) Å, α = 72.076(2)°, β = 85.408(2)°, γ = 69.279(2)°, V = 3425.3(3) Å 3 , Z = 1, R gt ( F ) = 0.0446, wR ref ( F 2 ) = 0.1314, T = 123 K Figure 1: A view of (a) the asymmetric unit, (b) the coordination sphere of K1 and (c) the full tetramer (H-atoms and n -hexane omitted for clarity, ter (2,6-bis(2,4,6-trimethylphenyl)phenyl) and i Pr substituents are depicted as wireframes). .

Source: Zeitschrift für Kristallographie - New Crystal Structures

DOI: 10.1515/ncrs-2025-0439

Authors: Karsten Paul Lüdtke, Axel Schulz, Lilian Sophie Szych

Institutions: University of Rostock, Leibniz Institute for Catalysis, University of Münster

Language: English

Topic: Crystal structures of chemical compounds

Subfield: Inorganic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: gold

Estimated APC paid: $848

Funder: Fonds der Chemischen Industrie