Work

Electric Field-Driven Melt Jetting Polycaprolactone Rotational Printing of Fully Degradable Vascular Stents and Mechanical Characterization

Year: 2025

Type: article

Abstract: Addressing technical challenges in personalized fabrication and mechanical regulation of bioresorbable vascular scaffolds, this study pioneers an electric field-driven melt jetting rotational printing technique to fabricate polycaprolactone (PCL) scaffolds (Ø3-8 mm). Multiscale characterization confirms a rhombic mesh macrostructure with uniform fibers and fusion-enhanced nodal junctions, demonstrating synergistic control of electrohydrodynamic forces and surface tension over microfiber deposition. Mechanical testing reveals triphasic tensile behavior (elastic-plastic-fracture), where 5 mm scaffolds exhibit 38% enhanced peak load due to superior interfacial bonding and densified geometry, while 8 mm counterparts suffer premature failure from structural weakening. Fractography identifies brittle fracture initiation at stress-concentrated nodes versus ductile dominance in straight segments, confirming co-regulation by intrinsic material properties and architecture. Compression tests demonstrate characteristic load-holding-recovery behavior, with 20% increased load-bearing capacity and enhanced elastic recovery in larger scaffolds. This work establishes a structure-property correlation framework for optimizing degradable vascular implants, providing novel methodologies and theoretical foundations for clinical compatibility.

Source: Polymers

DOI: 10.3390/polym18010074