Year: 2025
Type: article
Abstract: Metal hydrides are traditionally known for their hydrogen storage abilities under specific temperature and pressure conditions. However, recent studies suggest their possible applications as a catalyst and catalyst promotor. This article introduces metal hydride applications in three different areas: the hydrogenation and the dehydrogenation of Liquid organic hydrogen carriers, ammonia synthesis, CO2 hydrogenation and CO2 reduction. The key mechanisms explored include the direct participation of the absorbed lattice hydrogen in catalytic surface reactions, creation of new hydrogen transfer path between the hydrogen and the organic substrate, and surface decomposition of the parent hydride into highly active interfacial phases, such as Ni-LaN for ammonia, and Ni-O-La for CO2 hydrogenation. Case studies involving YH3 and LaNi5 illustrate how these materials function not merely as static hydrogen reservoirs but as dynamic systems that serve as hydrogen donors, and structural templates for generating unique active sites. This review highlights a paradigm shift in understanding metal hydrides as multifunctional materials that bridge the gap between hydrogen storage and heterogeneous catalysis.
Source: Ceramist
Authors: Sung Ju Han, Heung Nam Han, Jin Yoo Suh
Language: English
Subfield: Materials Chemistry
Field: Materials Science
Domain: Physical Sciences
Open Access status: diamond
Award: G2901667881
OpenAlex ID: W7118196016