Work

Nickel - Catalyzed Synthesis of Defined Cyclic Polyene Oligomers: An Architecture for Amorphous Charge Transport Materials

Year: 2026

Type: article

Abstract: High Resolution Image Download MS PowerPoint Slide We introduce a structural strategy to develop amorphous hole-transporting materials for organic electronics. Utilizing a highly selective nickel-catalyzed cycloaddition oligomerization of 1,6-diyne monomers containing triphenylamine (TPA) or N,N -diphenylnaphthalen-1-amine (DPNA) moieties afforded cyclic polyene oligomers ( 2a and 2b ) in high yields. These medium-sized oligomers are structurally defined, possessing narrow molecular weight polydispersities and adopting an unusual rigid, shrunken cyclic conformation. This feature enables dense accumulation of conductive TPA/DPNA moieties. The resulting materials exhibit excellent thermal stability and successfully maintain a desired amorphous-like morphology in the solid state. Hole-only devices constructed with these oligomers show effective electrical conductivity, achieving a high number of hole mobilities.

Source: ACS Applied Polymer Materials

DOI: 10.1021/acsapm.5c04461

Authors: Yuga Tsunoda, Kouta Ibe, Sentaro Okamoto

Institution: Kanagawa University

Language: English

Topic: Organic Electronics and Photovoltaics

Subfield: Electrical and Electronic Engineering

Field: Engineering

Domain: Physical Sciences

Open Access status: hybrid

Estimated APC paid: $4,500

Funders: Toshiaki Ogasawara Memorial Foundation, Japan Society for the Promotion of Science