Beyond the Lindlar catalyst: highly-oxidized Pd single atoms as promoters for alkyne semi-hydrogenation
Year: 2026
Type: article
Abstract: A “grafting-then-coordination” strategy was proposed to construct Pd/C-NH 2 featuring coexisting tetravalent Pd single atoms (Pd IV SAs) and Pd nanoparticles (Pd NPs), which achieves inhibitor-free, highly efficient hydrogenation of steroidal alkynes.
Source: Chemical Science
DOI: 10.1039/d5sc08632a
Language: English
Subfield: Organic Chemistry
Field: Chemistry
Domain: Physical Sciences
Open Access status: diamond
OpenAlex ID: W7119047584
