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Alternative method for synthesis of tetracarboxylic acids with cycloaliphatic fragments

Year: 2025

Type: article

Abstract: The tetracarboxylic acids containing a cycloaliphatic fragment are promising monomers for semi-aromatic polymers of a series of polyimides, polyesters, and polyetherimides. An alternative method has been developed for their synthesis. The method demonstrates the possibility of performing alkylation and acylation reactions in sequence. The choice of the combination of methods for the oxidation of the acyl and methyl groups has been confirmed by quantum chemical calculations.

Source: From Chemistry Towards Technology Step-By-Step

DOI: 10.52957/2782-1900-2025-6-4-117-125

Authors: Anastasia Firstova, Dmitry Ogorodnikov, Yulia Yusifova, Evgeny Kofanov, Anton Lebedev

Institutions: Yaroslavl State Technical University, Yaroslavl State University

Language: English

Topic: Synthesis and properties of polymers

Subfield: Polymers and Plastics

Field: Materials Science

Domain: Physical Sciences

Open Access status: bronze

OpenAlex ID: W7119903321

FWCI:

Cites: 18

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