Suppression of Macroscopic Phase Separation in Polymer Blends Confined within the Interstitial Pores of Dense Nanoparticle Packings
Year: 2026
Type: article
Abstract: Polymer blends often suffer from macroscopic phase separation due to incompatibility, with conventional compatibilization techniques relying on kinetically trapped, inhomogeneous structures. Here we show that confining prototypical immiscible polymers, polystyrene (PS) and polymethyl methacrylate (PMMA), within the interstices of a nanoparticle packing effectively suppresses phase separation at the macroscopic scale. By varying the confinement ratio (Γ, the ratio of a polymer’s radius of gyration to the nanoparticle packing’s pore radius) between 0.6 and 2.2 through modulating the polymer molecular weight and nanoparticle diameters (7 nm - 61 nm), we establish confinement-driven morphology transition. Systems with Γ <0.9 display macroscopic phase separation, akin to bulk blends, as observed via optical and scanning electron microscopy. In contrast, for Γ>2, macroscopic phase separation is suppressed across all microscopy scales. Passivating SiO2 nanoparticles with chlorotrimethylsilane, which weakens PMMA-SiO2 interactions, induces macrophase separation across all tested Γs, underscoring the critical role of polymer-nanoparticle interactions in phase behavior. We propose a pore-scale segregation mechanism in which PMMA preferentially wets the nanoparticle surfaces while PS localizes to pore centers. Selective solvation experiments indicate the presence of a continuous PMMA layer, consistent with a core-shell morphology validated by resonant soft x-ray scattering. These findings provide a new strategy to compatibilize polymer blends through confinement with implications for the design of nanocomposite films with tunable properties.
Source: ACS Nano
Language: English
Subfield: Polymers and Plastics
Field: Materials Science
Domain: Physical Sciences
Open Access status: green
OpenAlex ID: W7123352243