Year: 2026
Type: article
Abstract: We report the first observation of room-temperature phosphorescence (RTP) of quinine sulfate (QS) in poly (vinyl alcohol) (PVA) films. Steady-state and time-gated measurements were performed to characterize the phosphorescence spectra, anisotropies, and lifetimes to estimate the phosphorescence properties. The RTP response of organic emitters in polymer matrices is particularly sensitive to ambient humidity and oxygen levels. Hence, to assess the environmental stability of the system, QS-doped PVA films were cast from a single batch and divided into paired specimens, one of which was encapsulated with a pressure-sensitive laminate, while the other one was left non-laminated. Over 14 days under ambient laboratory conditions, the absorbance and fluorescence of both films remained unchanged, whereas the exhibited phosphorescence diverged significantly. The unlaminated film exhibited a progressive loss of afterglow intensity, a noticeable red shift in the phosphorescence spectrum, and a pronounced shortening of the phosphorescence lifetime, while the laminated film retained its initial RTP intensity, spectral profile, and lifetime throughout the entire experiment.
Source: Optics
DOI: 10.3390/opt7010007
Institution: Texas Christian University
Language: English
Subfield: Materials Chemistry
Field: Materials Science
Domain: Physical Sciences
Open Access status: gold
Estimated APC paid: $1,448
Award: G4371645641
OpenAlex ID: W7123477257