Work

Waste PU-derived PDMS/ZIF-8/bentonite composite sponge for reusable oil sorption

Year: 2026

Type: article

Abstract: Rapid urbanization and population growth have intensified oil pollution, highlighting the need for efficient, selective, and multifunctional oil sorbents. In this study, a cost-effective hydrophobic composite was developed from waste polyurethane (PU) sponge with a durable 3D macroporous structure. The sponge was modified via dip-coating with zeolitic imidazolate framework (ZIF-8), bentonite, and polydimethylsiloxane (PDMS) to enhance hydrophobicity. The resulting PDMS/ZIF-8/bentonite-incorporated PU (ZBPU) sponge was characterized using powder X-ray Diffraction, Fourier Transform Infrared spectroscopy, and Scanning Electron Microscopy analyses. Contact angle measurements confirmed a hydrophobicity for the prepared ZBPU-3 sponge, indicating its suitability for oil separation applications. Sorption performance was tested with canola oil, methylene blue dye, and non-aqueous phase liquids (chloroform, toluene, xylene, benzene). ZBPU-3 exhibited an oil sorption capacity of 0.97 g/cm 3 , about twice that of pristine PU, and maintained effective performance for up to five sorption–desorption cycles, with oil uptake governed mainly by physical interactions. • The PU sponge was fabricated via a dip-coating technique with ZIF-8, bentonite, and PDMS. • The hydrophobicity of ZBPU-3 was significantly enhanced, as evidenced by water contact angle. • ZBPU-3 sponge exhibited superior performance in removing oil particles from aqueous phase. • ZBPU-3 sponge maintained effective performance for up to five absorption–desorption cycles. • ZBPU-3 sponge serves as a multifunctional material, recovering MB dye and organic solvents.

Source: Journal of Hazardous Materials Letters

DOI: 10.1016/j.hazl.2026.100175