Work

Upcycling Industrial Polyphenylsulfone Waste into a High-Performance, Non-fluorinated Photothermal Membrane for Sustainable Desalination

Year: 2026

Type: article

Abstract: High Resolution Image Download MS PowerPoint Slide Photothermal membrane distillation (PMD) offers a sustainable pathway for freshwater production, yet its progress depends on developing high-performance membranes made from environmentally benign materials. To address the growing concern over the environmental persistence of fluorinated polymers, this study utilizes non-fluorinated, postindustrial polyphenylsulfone (w-PPSU) waste as a sustainable polymer source for fabricating photothermal membranes. Electrospun w-PPSU nanofibers were surface-modified with magnetite/black titania (Fe 3 O 4 /b-TiO 2 ) nanocomposites synthesized at varying b-TiO 2 concentrations and subsequently sealed with a thin hydrophobic polydimethylsiloxane (PDMS) coating. The best-performing membrane (M-F/bT-50) demonstrated rapid solar-driven heating, elevating its surface temperature to 91.1 °C within 120 s under 1 kWm –2 irradiation. In desalination tests at a minimal temperature difference (Δ T = 15 °C), this membrane achieved a water flux of 3.27 Lm –2 h –1, a salt rejection of 99.74%, and a photothermal conversion efficiency of 69.87%. Furthermore, the membrane maintained performance over multiple acidic cleaning cycles, demonstrating high flux recovery and regenerability. This work not only introduces an effective material system for efficient desalination but also establishes a viable pathway for valorizing industrial polymer waste into advanced, environmentally responsible technologies, contributing directly to the principles of a circular economy.

Source: ACS Environmental Au

DOI: 10.1021/acsenvironau.5c00231