Year: 2026
Type: article
Abstract: The origin of a transformation's stereoselectivity is one of the core issues in asymmetric catalysis. Herein, we propose a competitive induction model which is demonstrated to explore the origin of stereoselectivity for the Cu(I)/NHC‐catalysed [3+3] annulation. Computational studies reveal that chirality is jointly induced during a reversible nucleophilic addition, while the final stereochemical outcome is exclusively governed by the NHC organocatalyst in a subsequent irreversible step. More details are discussed in the article by Bai et al . on pages 508—516. image
Source: Chinese Journal of Chemistry
DOI: 10.1002/cjoc.70482
Language: English
Subfield: Organic Chemistry
Field: Chemistry
Domain: Physical Sciences
Open Access status: bronze
OpenAlex ID: W7124451909
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