Higher-order Derivative Voltabsorptmetry of Tris(acetylacetonato)iron (III) Complex in Acetonitrile
Year: 2026
Type: article
Abstract: A voltaborptmetric property of tris(acetylacetonato)iron (III) (Fe(acac)3) in acetonitrile in an optically transparent thin layer cell was investigated.The obtained electronic absorption spectra were analyzed using the higher-order derivative conversion (HODC) up to the eighth order.The Nernst equation can analyze the potential dependence of the sub-peak obtained by the HODC, and the HODC method is shown to be effective for studying the spectroelectrochemistry of metal complexes dissolved in non-aqueous systems.
Source: Electrochemistry
Author: Shinya KISHIOKA
Institution: Gunma University
Language: English
Subfield: Electrochemistry
Field: Chemistry
Domain: Physical Sciences
Open Access status: gold
Estimated APC paid: $1,130
OpenAlex ID: W7124467086