Work

Multiphase catalytic system enhancement of hydrogen storage performance in MgSc alloy via nanosheet-clustered NiO

Year: 2026

Type: article

Abstract: Catalytic modification can effectively reduce the kinetic barriers and enhance the reaction rate of Mg-based hydrogen storage materials. In this study, nanosheet-clustered NiO catalyst is synthesized and incorporated into MgSc solid solution alloy. The hydrogen de/sorption properties are optimized through the effects of in-situ generated nanocatalysts and external addition catalysts. Results indicate the in-situ formation of nanosized ScH 2 catalytic phases within MgSc alloy matrix, along with the generation of Mg 2 Ni/Mg 2 NiH 4 nanophases through the reaction between NiO and Mg. In addition, a small amount of Ni maintains nanoparticles morphology through stabilization by Ni/MgO coupling effect. At 300 °C, the hydrogen storage capacity of 5 wt% NiO-modified is reached at 5.44 wt%. And the dehydrogenation capacity achieves 3.05 wt% within 5 min. The formation of multiphase interfaces during hydrogenation establishes both abundant hydrogen diffusion channels and high-density active sites. In addition, dehydrogenation performance is remarkably enhanced by the synergistic catalytic between Ni-mediated hydrogen spillover and the hydrogen pump effect of ScH 2 and Mg 2 Ni/Mg 2 NiH 4 .

Source: Journal of Alloys and Compounds

DOI: 10.1016/j.jallcom.2026.186221