Year: 2026
Type: article
Abstract: The origin of the viscoelastic behavior that many nanoparticles display during diffusive motion is unknown. Such dynamics are difficult to record without sophisticated methods that combine a suitable observation window of motion in time with high image resolution. Herein, we study and describe the diffusion of two types of particles in the form of emulsion droplets in situ via liquid phase TEM. For both, the observed particle motion in solution is anomalous (non-Brownian) and is either sub- or super-diffusive. Fractional Brownian motion (fBm) and random walks on fractals (RWF) are the two potential mechanisms. It can be challenging to differentiate these since they may have the same position or velocity autocorrelation function, but they diverge in the average number of sites visited, which is connected to the fractal dimension of the walk. We conclude that droplet-surface interactions and electron beam fluence create a fractal energy landscape yielding peculiar dynamics.
Source: Small
Language: English
Subfield: Modeling and Simulation
Field: Mathematics
Domain: Physical Sciences
Open Access status: hybrid
Estimated APC paid: $5,790
Awards: G1169090945, Reshaping Recyclable Thermosets, Graduate Research Fellowship Program (GRFP), G3454132534, G4054052150, G4285583887, Acquisition of a K2 Camera for Soft Matter Transmission Electron Microscopy, MRSEC: Center for Multifunctional Materials, G513586523, G5218300437, G712509569, G7452299184, G7461832402
OpenAlex ID: W7126162111