Year: 2026
Type: article
Abstract: ABSTRACT π‐Conjugation, π–π stacking, and long‐range order play a central role in determining charge transport efficiency in organic materials. Covalent organic frameworks (COFs), which uniquely integrate these key structural and electronic features, have emerged as a promising platform for the development of novel electrically conductive organic materials. Intraframework π‐conjugation has shown to play a key role in improving charge carrier mobility. Here, we report Joa‐COF‐2 , a 3D COF lacking extended intraframework π‐conjugation, yet exhibiting a remarkable charge carrier mobility of 14 ± 1 cm 2 V −1 s −1 . Joa‐COF‐2 adopts an 11‐fold interpenetrated dia topology, featuring a tight interframework π–π stacking, which enables efficient charge transport in the absence of intraframework π‐conjugation.
Source: Advanced Materials
Language: English
Subfield: Materials Chemistry
Field: Materials Science
Domain: Physical Sciences
Open Access status: hybrid
Estimated APC paid: $6,070
Funders: European Commission, Eusko Jaurlaritza, Euskal Herriko Unibertsitatea, Ministério da Ciência, Tecnologia e Ensino Superior, Centro de Investigação em Materiais Cerâmicos e Compósitos, HORIZON EUROPE Framework Programme, Engineering and Physical Sciences Research Council, Fundação para a Ciência e a Tecnologia, European Regional Development Fund, Agencia Estatal de Investigación, Fuel Cell Technologies Program, European Social Fund, H2020 European Research Council
Awards: G1006350169, G1120613499, G1175115578, G131536089, G1338257350, G1416831901, G1622782223, G1659629902, G1918496035, G210041235, G2157332709, G2262748287, G2281333282, G24120701, G2521182000, G2601397997, G2756310335, G2826743980, G2840769958, G2845679602, G294895050, G2998721294, G300979063, G308504231, G3144760282, G3283876815, G3292045690, G3383821569, G3428307696, G34346518, G3480869486, G3681454997, G4033406476, G4042783231, G4046065984, G404710190, G410571670, G425668148, G434337789, CICECO-Instituto de Materiais de Aveiro, G4448273050, G451917667, G4526231891, G4560261267, G464105488, A New Correlative Approach for Structure Determination & Imaging of Molecular Materials, Metal Atoms on Surfaces & Interfaces (MASI) for Sustainable Future, G5049803760, G5080475149, G5138472656, G5195188938, G523076202, G5262952806, CICECO – Instituto de Materiais de Aveiro, G5385376234, G546199279, G5539308778, G5616161182, G5933510654, G5943232429, G5967599077, G6033112984, G6200043914, G6218905885, G6410266313, G6502585861, G665356208, G6997658380, G7009239949, G7084143925, G7127239378, G7162266856, e-Sequence: a sequential approach to engineer heteroatom doped graphene nanoribbons for electronic applications, G7403097962, G7434936867, G750559012, G7752152075, G808304229, G811335871, G8118709007, G8222313181, G8618118650, G8888022036, G929308097
OpenAlex ID: W7127288275