Theoretical investigations on the activation of Silanes by rare-earth complexes: Mechanisms, bonding, and catalytic implications
Year: 2026
Type: article
Abstract: The activation of E–H bonds (E = Si, B, C, etc.) by rare-earth complexes has emerged as a central topic in organometallic chemistry, due to its mechanistic diversity and its relevance to catalytic transformations. Among these, the cleavage and functionalization of silanes (Si H) by lanthanide and related complexes have drawn increasing attention, both experimentally and theoretically. Recent computational studies have unveiled a wealth of mechanistic insights, revealing that σ-bond metathesis constitutes the dominant pathway for Si H activation across most rare-earth elements, contrasting with oxidative addition mechanisms typical of transition metals. This review summarizes theoretical developments devoted to the activation of silanes by rare-earth complexes, emphasizing density functional theory (DFT) analyses, bonding descriptions, and trends across the lanthanide series. Theoretical models, including Cp₂LnH and bis(amidinate) systems, are discussed in connection with experimental data, providing a coherent picture of structure–reactivity relationships. Finally, perspectives on ligand effects, periodic trends, and catalytic applications are outlined to guide future design of rare-earth-based hydrosilylation catalysts.
Source: Coordination Chemistry Reviews
Language: English
Subfield: Organic Chemistry
Field: Chemistry
Domain: Physical Sciences
Open Access status: hybrid
Estimated APC paid: $5,740
OpenAlex ID: W7127370401